The transition from fossil fuels to sustainable energy sources can only be achieved with targeted upgrades in energy storage technology. Conventional batteries are limited in capacity by their volume. To address this, redox flow batteries were introduced, decoupling energy storage from the physical size of the battery cell. However, the poor solubility of redox species restricts the energy density achievable with this technology.

To overcome this limitation, this project will investigate a novel energy storage method known as a redox-mediated battery. Part of the project will involve setting up a simple experimental system to study redox-mediated reactions and to capture various kinetic and diffusion parameters. To decouple the effects of individual parameters, a model will be developed and validated against experimental results.

The initial step will focus on simple redox-mediated reactions without any mass transfer limitations impeding the reaction, progressing to more complex systems involving additional mass transfer limitations as the project advances. These findings will directly contribute to building both a numerical model (in Julia preferably) and an experimental setup for testing this novel battery technology. You will gain hands-on experience in both the experimental testing of batteries and modeling the transport phenomena involved.

If time permits, an extension of the project could involve investigating the spatial dependence of the reaction rate within the system using SEM (Scanning Electron Microscopy) analysis.

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n a Molten Salt Reactor, solid fission particles tend to sediment on a surface, such as the reactor vessel and heat exchagers, deteriorating the properties of the structural materials in the reactor. In this unique project, the PhD student will study the sedimentation of these particles and its underlying mechanisms in high temperature molten salts. The approach is to develop an experimental facility, where parameters such as temperature, flow and materials can be changed and to extract data on the tendency of solid fission products to sediment under a range of conditions. The acquired data will then be used to validate own-developed numerical and physical models for sedimentation, so that a solid calculated estimate can be made in real cases and real situations. This PhD project is part of the recently granted EC project "ENDURANCE", which is a follow-up project of SAMOFAR and SAMOSAFER, both projects focussed on thorium-based molten salt reactors.
The PhD student will be part of this international consortium and cooperate with the other members of the project, the technicians in our research group and with the principle investigator. Start-date of the project is October 1, 2024.
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LBM is mostly used for fluid flow and scalar transport (heat, species). A lesser known feature, however, is the fact that the method can also be used for neutron transport and be coupled to momentum and energy transport. Recently, researchers have extended the method for neutronics. In this project, the method will be applied to either a molten-salt reactor case or the DIPR, a reactor in which radio-isotopes can be produced. If you are interested, we can start a discussion on the exact topic to be done.

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The molten salt reactor is a very safe and sustainable nuclear reactor. One of the key safety features is the freeze plug, which can be used in case of an emergency situation. The plug is kept frozen actively and melts as soon as the active freezing stops (e.g. by a station blackout). The plug needs to melt quickly to drain the reactor vessel as fast as possible. The angle of the freeze plug is important because the melting occurs partially by natural circulation. Hence, the orientation of gravity with respect to the plug is important.

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The molten salt reactor is a very safe and sustainable nuclear reactor. The reactor fuel is liquid instead of solid, making this type of reactor very safe. Freezing may occur in the heat exchanger, risking blockage of the cooling channels. To understand freezing under turbulent conditions, one needs either perform experiments or simulations. This project deals with LES simulations under turbulent conditions, thereby using the lattice-Boltzmann method. This method can easily be implemented on GPU's, so that large calculations speeds can be accomplished. Challenges in this project are the development of such an efficient code in the Julia language, in conjunction with Large Eddy Simulations (to model the turbulence).

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During the operation of molten salt reactors valuable fission products are formed. Due to the extreme working environment, a removal of those particles is challenging. One promising technology to remove fission products is the separation via helium bubbling. Here, the fission particles are adhering to the helium bubbles, from which they are getting transported to the liquid surface, from where they can get separated. Part of the research is building up a setup for experiments with molten salts, in which the flow characteristics and particle removal are determined by methods like the Laser-Doppler-Anemometry and Particle Image Velocimetry. In a first step, experiments will be conducted at room temperature in water and a model system consisting of water/glycerol, which is well established to mimic the characteristics of the molten salt. From these results, operating conditions will be determined, which will be used in a later step with the molten salt setup at elevated temperatures. Moreover, numerical work in the form of CFD-simulations can be included to obtain additional information about the phenomena inside the reactor.

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Supercritical fluids are being used in a wide range of applications such as chemical processes (e.g. extration) and energy processes (e.g. heat removal, nuclear reactors). In this study, the student is going to use and extend the lattice-Boltzmann Method for supercritical fluids and study the phenomenon of natural convection under laminar (and perhaps) turbulent conditions.

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